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Date
Winner
Loser
Tournament
Round
Score
2008-02-02
Aleksandra Wozniak (140)
Vilmarie Castellvi (380)
Fed Cup G1 PO: CAN vs PUR
RR
3-6 6-1 7-5
2008-02-01
Teliana Pereira (221)
Vilmarie Castellvi (380)
Fed Cup G1 RRA: PUR vs BRA
RR
6-4 6-0
2008-01-31
Vilmarie Castellvi (380)
Maria Eugenia Roca Recarey (873)
Fed Cup G1 RRA: PUR vs URU
RR
6-3 6-0
2008-01-30
Vilmarie Castellvi (380)
Rossana De Los Rios (120)
Fed Cup G1 RRA: PUR vs PAR
RR
7-5 6-3
2007-04-21
Vilmarie Castellvi (245)
Melisa Miranda Otarola (633)
Fed Cup G1 PO: PUR vs CHI
RR
6-1 1-6 7-5
2007-04-19
Jorgelina Cravero (142)
Vilmarie Castellvi (245)
Fed Cup G1 RRB: ARG vs PUR
RR
6-0 6-2
2007-04-18
Mariana Duque Marino (273)
Vilmarie Castellvi (245)
Fed Cup G1 RRB: PUR vs COL
RR
5-7 6-4 6-4
2006-04-22
Vilmarie Castellvi (176)
Erika Clarke Magana (642)
Fed Cup G1 PO: MEX vs PUR
RR
6-1 6-1
2006-04-21
Jenifer Widjaja (291)
Vilmarie Castellvi (176)
Fed Cup G1 RRB: BRA vs PUR
RR
2-6 6-4 7-5
2006-04-20
Vilmarie Castellvi (176)
Paula Catalina Robles Garcia ()
Fed Cup G1 RRB: COL vs PUR
RR
6-1 6-1
2005-10-31
Sofia Arvidsson (75)
Vilmarie Castellvi (164)
Quebec City
R32
6-2 7-5
2005-10-03
Sania Mirza (37)
Vilmarie Castellvi (173)
Japan Open
R32
6-1 6-3
2005-09-26
Catalina Castano (65)
Vilmarie Castellvi (166)
Seoul
R32
6-1 6-3
2005-09-19
Karolina Sprem (81)
Vilmarie Castellvi (173)
Kolkata
R16
7-5 3-6 6-1
2005-09-19
Vilmarie Castellvi (173)
Emmanuelle Gagliardi (99)
Kolkata
R32
6-4 6-4
2005-07-09
Wynne Prakusya (388)
Vilmarie Castellvi (160)
Fed Cup WG2 PO: PUR vs INA
RR
6-3 6-4
2005-07-09
Romana Tedjakusuma (501)
Vilmarie Castellvi (160)
Fed Cup WG2 PO: PUR vs INA
RR
6-2 6-2
2005-04-23
Vilmarie Castellvi (143)
Aleksandra Wozniak (370)
Fed Cup G1 PO: PUR vs CAN
RR
7-5 4-6 11-9
2005-04-22
Vilmarie Castellvi (143)
Celina Grissi ()
Fed Cup G1 RRA: PUR vs BOL
RR
6-0 6-2
2005-04-21
Vilmarie Castellvi (143)
Daniela Munoz Gallegos (431)
Fed Cup G1 RRA: PUR vs MEX
RR
6-2 6-3
2005-04-20
Vilmarie Castellvi (143)
Estefania Craciun (655)
Fed Cup G1 RRA: URU vs PUR
RR
6-0 7-6(4)
2005-02-14
Zsofia Gubacsi (157)
Vilmarie Castellvi (140)
Bogota
R32
6-4 7-5
2004-08-09
Milagros Sequera (74)
Vilmarie Castellvi (137)
Vancouver
R16
6-1 7-5
2004-08-09
Vilmarie Castellvi (137)
Marie Eve Pelletier (188)
Vancouver
R32
6-0 6-4
2004-07-19
Elena Likhovtseva (39)
Vilmarie Castellvi (155)
Los Angeles
R64
6-3 6-2
2004-04-24
Vilmarie Castellvi (176)
Andrea Koch Benvenuto ()
Fed Cup G1 PO: PUR vs CHI
RR
7-5 6-4
2004-04-22
Daniela Munoz Gallegos ()
Vilmarie Castellvi (176)
Fed Cup G1 RRA: MEX vs PUR
RR
7-6(2) 6-2
2004-04-21
Vilmarie Castellvi (176)
Karen Castiblanco ()
Fed Cup G1 RRA: COL vs PUR
RR
6-3 6-1
2004-04-20
Vilmarie Castellvi (176)
Liz Cruz ()
Fed Cup G1 RRA: ESA vs PUR
RR
6-2 6-1
2003-04-27
Vilmarie Castellvi ()
Avel Romaly Coronado (983)
Fed Cup G2 RRA: PUR vs VEN
RR
6-2 6-0
2003-04-26
Vilmarie Castellvi ()
Andrea Brenes ()
Fed Cup G2 RRA: PUR vs CRC
RR
6-0 6-1
2003-04-24
Vilmarie Castellvi ()
Maria Teresa Salame ()
Fed Cup G2 RRA: PUR vs ECU
RR
6-2 6-1
2003-04-23
Vilmarie Castellvi ()
Natalia Baez ()
Fed Cup G2 RRA: PUR vs DOM
RR
6-1 6-0
1999-04-16
Sonya Jeyaseelan (104)
Vilmarie Castellvi ()
Fed Cup G1 RRB: CAN vs PUR
RR
6-3 6-4
1999-04-15
Karem Harboe (855)
Vilmarie Castellvi ()
Fed Cup G1 RRB: CHI vs PUR
RR
5-7 7-5 7-5
1999-04-14
Vanessa Menga (167)
Vilmarie Castellvi ()
Fed Cup G1 RRB: BRA vs PUR
RR
6-3 7-5
1999-04-13
Maria Vento Kabchi (78)
Vilmarie Castellvi ()
Fed Cup G1 RRB: PUR vs VEN
RR
6-1 6-3
1997-05-01
Carmina Giraldo (383)
Vilmarie Castellvi ()
Fed Cup G1 RRB: COL vs PUR
RR
6-2 7-6(8)
1997-04-30
Vilmarie Castellvi ()
Mariela Salinas ()
Fed Cup G1 RRB: PUR vs VEN
RR
7-6(5) 6-0
1997-04-29
Barbara Castro (460)
Vilmarie Castellvi ()
Fed Cup G1 RRB: CHI vs PUR
RR
6-2 6-2
1997-04-28
Carla Rodriguez ()
Vilmarie Castellvi ()
Fed Cup G1 RRB: PER vs PUR
RR
6-3 7-5
1995-03-29
Vilmarie Castellvi ()
Beverly Corbie ()
Fed Cup G2 RRD: TRI vs PUR
RR
3-6 6-2 6-0
1995-03-28
Vilmarie Castellvi ()
Ann Simons ()
Fed Cup G2 RRD: PUR vs BAH
RR
3-6 6-2 6-1