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Date
Winner
Loser
Tournament
Round
Score
2014-04-07
Caroline Garcia (74)
Florencia Molinero (184)
Bogota
R32
6-3 6-4
2013-04-20
Laura Robson (38)
Florencia Molinero (224)
Fed Cup WG2 PO: ARG vs GBR
RR
6-1 6-1
2013-02-09
Florencia Molinero (217)
Sofia Arvidsson (38)
Fed Cup WG2 R1: ARG vs SWE
RR
6-3 2-6 6-1
2013-02-09
Johanna Larsson (71)
Florencia Molinero (217)
Fed Cup WG2 R1: ARG vs SWE
RR
6-3 6-2
2012-04-21
Florencia Molinero (180)
Qiang Wang (223)
Fed Cup WG2 PO: ARG vs CHN
RR
6-3 6-4
2012-04-21
Yi Miao Zhou (473)
Florencia Molinero (180)
Fed Cup WG2 PO: ARG vs CHN
RR
7-6(1) 2-6 6-3
2012-02-04
Florencia Molinero (184)
Mariana Duque Marino (195)
Fed Cup G1 PO: ARG vs COL
RR
3-6 6-2 6-1
2012-02-03
Florencia Molinero (184)
Patricia Ku Flores (572)
Fed Cup G1 RRA: ARG vs PER
RR
7-5 6-4
2012-02-02
Florencia Molinero (184)
Stephanie Dubois (87)
Fed Cup G1 RRA: CAN vs ARG
RR
6-2 6-2
2012-02-01
Florencia Molinero (184)
Simone Pratt ()
Fed Cup G1 RRA: ARG vs BAH
RR
6-2 6-0
2011-02-05
Florencia Molinero (194)
Catalina Castano (190)
Fed Cup G1 PO: ARG vs COL
RR
7-6(5) 6-1
2011-02-04
Florencia Molinero (194)
Patricia Ku Flores (769)
Fed Cup G1 RRA: ARG vs PER
RR
6-2 6-3
2011-02-03
Florencia Molinero (194)
Montserrat Gonzalez ()
Fed Cup G1 RRA: ARG vs PAR
RR
6-7(5) 6-1 6-3
2011-02-02
Florencia Molinero (194)
Maria Ines Deheza ()
Fed Cup G1 RRA: ARG vs BOL
RR
6-4 6-3
2011-01-03
Sabine Lisicki (175)
Florencia Molinero (185)
Auckland
R32
6-1 6-3